35. 1985 Villanova Wildcats
Key Players: Ed Pinckney, Dwayne McClain, Harold Pressley
Finish: Won the national championship
Video: CLICK HERE TO WATCH A CLASSIC MOMENT
No one gave the Wildcats a chance to win against the Georgetown Hoyas in the '85 title game. No ooooooone! Yet, they pulled off one of the biggest upsets in sports history when they shot an unbelievable 78.6 percent from the field and earned a two-point victory over Patrick Ewing & Co. It was the true definition of "March Madness."