Episode: "Supersmurf" (Season 1,Episode 12)
Although Smurfette could practically control the entire Smurf village if she wanted to (she was made by Gargamel to destroy the village after all), not everyone can be manipulated by her allure. Case in point: In "Supersmurf," Smurfette attempts to reclaim a bunch of food stolen from the Smurf village by an ogre named Bigmouth. He calls Smurfette a Smurf which leads to this response: "Oh, you silly ogre. I'm not a Smurf ,I'm a Smurfette. Wanna see?" The ogre ponders the question for a moment before saying no, but what if he had said yes? The possibilities are gross.