Played By: Michelle Pfeiffer
Movie: Batman Returns (1992)

In Tim Burton's gothic Batman universe, Selina Kyle is positively unhinged, her personality disorder represented by her oddly stitched, patchwork yet form-fitting costume, one of the hottest in all of superhero cinema. She's also a more vengeful take on the character, spending most of Batman Returns expending her (literal) nine lives in an effort to take out the murderous millionaire (Christopher Walken) who tried to kill her, all while driving both Bruce Wayne and Batman (Michael Keaton) wild. Everything about her is over the top, from the purrs to the whip, but Michelle Pfeiffer makes it all work, and then some.