14. Anya Jenkins (Emma Caulfield) as an Angel in Buffy the Vampire Slayer
Episode: "All the Way"
Air Date: 10/30/01
Emma Caulfield hit her sexiness peak as culturally-confused former demon Anya during Buffy's first season on UPN, as evidenced by this Halloween episode, in which she dressed as an angel. The kind that, in her words "Don't have wings, just skate around with perfect hair, fighting crime."