This week, The CW network is gearing up for a slew of season premieres: Gossip Girl, 90210, and The Vampire Diaries, to name a few, three primetime dramas that are jam-packed with gorgeous women. But that's nothing new for The CW. Throughout the years, many of the stunning young starlets who've appeared on the network have gone on to become some of the sexiest women in Hollywood—Kristen BellAmber Heard and Blake Lively to name a few.

So before you watch the channel's leading ladies continue stirring up trouble on their respective shows, take a look back at some of the hottest women in the history of The CW.