37. Elizabeth Taylor
Most Infamous Moment: She married and divorced Richard Burton twice between 1964 to 1976.
Elizabeth Taylor was known for her extravagance. Everything she had was in excess. Hell, she even had double eyelashes! But it was her eight marriages with seven men, including Conrad Hilton and Michael Wilding, that set her apart. When asked why she married so often, Taylor replied, "I was taught by my parents that if you fall in love, if you want to have a love affair, you get married. I guess I'm very old-fashioned."