#9: Kraven the Hunter (Amazing Spider-Man #294)
Kraven was a bum, plain and simple. He prided himself as a fierce hunter, but he dressed like Zsa Zsa Gabor and was usually defeated by Spider-Man just as easily. And that was usually the routine with Kraven until one day he got pissed and shot Spider-Man and then proceeded to bury him alive. Pretty good plan, right? What’s even stranger is that Kraven then started to dress like Spider-Man and fight crime. Satisfied with what he viewed as a victory over the wallcrawler, Kraven decided he could prove nothing more and ended his own life with a shotgun.