Release Year: 1963
Costume Designer: Jocelyn Richards
Who vs. Who: James Bond (Sean Connery) vs. Donald Grant (Robert Shaw)
Agent 007 always makes kicking ass and bagging international beauties look damn good. In From Russia with Love, Sean Connery plays James Bond with his trademark even keel, but this oft-celebrated trainbound smackdown with the villainous Robert Shaw shows 007's bruiser side. Once victory is his, though, J-Bond buttons his suit jacket, naturally. Being a stud is a 24/7 job.