Aired: 2001-2006

Sydney Bristow is the name, and sexy espionage is her game. The superspy takes dangerous missions using different aliases in search of artifacts from the Renaissance period that supposedly hold the answer to life's secrets. The show's real catch, however, is seeing Jennifer Garner in hot little outfits (every kind your dirty mind can think of) and kicking the bejeesus out of brolic dudes.

The Central Intelligence Agency (yes, the real CIA) featured Jennifer Garner in their 2004 recruitment video.