Films: The Princess Diaries (2001), The Princess Diaries 2: Royal Engagement (2004)

We'll admit it: we, too, thought Anne Hathaway would always be "that chick that was in The Princess Diaries." Little did we know that she had the ambition to shed her soft Disney ties with her topless scene in the controversial drama Brokeback Mountain. She's gone on to receive an Oscar nod and become one of the highest paid actresses in Hollywood.