Game: Vermont vs. Syracuse
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Despite losing top player Carmelo Anthony off of their National Title-winning squad from the year before, the Syracuse Orange were still favored to go far in the 2005 NCAA Tournament. The Catamounts had other plans, though, as their dynamic duo of Taylor Coppenrath and TJ Sorrentine stunned 'Cuse with an array of timely long-range shots. Sorrentine's 28-footer punctuated a stunning upset that nearly gave Gus Johnson a coronary, sending the defending champions home early.