11. Sterling Archer and Lana Kane on Archer
Played by: H. John Benjamin and Aisha Tyler
Sterling and Lana used to be an item, before the show started, but now they're rival secret agents. In addition to being the world's most dangerous secret agent, Archer is a selfish, shallow asshole—he'd gladly have sex with the foxy Lana because he'd gladly have sex with anyone foxy, and the innuendo he directs her way is always a bit mean.