The 15 Most Unexpected Celebrity Hook-Ups of 2012 Photo via Us Weekly

Wilmer Valderrama and Minka Kelly

When: March-August

On That 70s Show, his character Fez rarely got the girl, but earlier this year Wilmer Valderrama briefly scored one of hottest women on the planet, the beautiful Minka Kelly, who, just before that, had split with former fiancé Derek Jeter.

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