Played By: Angelina Jolie
Movie: Mr. And Mrs. Smith (2005)

The illicit romance and subsequent relationship that was borne out of Mr and Mrs. Smith will always be more famous than the film itself. Retrospectively, however, we really can't blame Brad Pitt for falling head over heels, especially when this particular role finds Angelina Jolie at her sexiest.

Whether she's pulling knives out of suggestive hiding spots in a floor-length dress, hitching said dress up while cradling a shotgun, or snapping necks in an S&M getup, Angelina-as-Jane is deadly as fuck, but it's for that same reason that she's irresistible. If we were filming those scenes alongside her, we'd have definitely fallen in love as well.