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Jennifer Garner

Jennifer Garner

Movie and TV Show: Catch Me if You Can and Alias

Before she became Ben Affleck's baby mama, the impossibly charming Jennifer Garner earned herself a Golden Globe for her role as CIA agent Sydney Bristow on J.J. Abrams' Alias. Also that year, this full-lipped beauty had a small role in Steven Spielberg's hit film, Catch Me if You Can. 

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