Only Jennifer Garner can make gold-digging look endearing. In the new comedy, Arthur (in theaters today), Garner plays a wealthy heiress arranged to marry an even wealthier playboy (played by Russell Brand) in order for both of them to come into even more money. In one of the movie's steamier scenes, the easily lovable Garner dons leather boots and lingerie to seduce Brand and, consequently, the audience as well. For those who follow the actress' tabloid life, the seductive character is a refreshing departure from Garner's real life persona as the hottest MILF dressed in J. Crew at the park. But whatever Mrs. Ben Affleck is or isn't wearing, one thing remains constant: She naturally charms our pants off. Need proof? These pictures should do the trick.